Polymers : Chemistry and Physics of Modern Materials, Third Edition Arrighi , Valeria , Cowie , J.M.G in pdf
this is the book Polymers : Chemistry and Physics of Modern Materials, Third Edition in pdf written by Arrighi , Valeria , Cowie , J.M.G published by CRC Press,2007 of professors of science faculties universities .
Information about the book
Language of the book: English language
Book Title: Polymers : Chemistry and Physics of Modern Materials, Third Edition
Scriptwriter: by Arrighi , Valeria , Cowie , J.M.G
Year of printing: by CRC Press,2007
File Format:PDF
Number of chapters: 242 CHAPTER
Number of chapters: 242 CHAPTER
Number of pages: 520 pages
File Size: 9,50MB
Contents
- Introduction
- Birth of a Concept
- Some Basic Definitions
- Synthesis of Polymers
- Nomenclature
- Average Molar Masses and Distributions
- Size and Shape
- Configuration
- The Glass Transition Temperature Tg and the Melting Temperature Tm
- Elastomers, Fibers, and Plastics
- Fiber-Forming Polymers
- Plastics
- Thermosetting Polymers
- Elastomers
- Step-Growth Polymerization
- General Reactions
- Reactivity of Functional Groups
- Carothers Equation
- Control of the Molar Mass
- Stoichiometric Control of Mn
- Kinetics
- Molar Mass Distribution in Linear Systems
- Average Molar Masses
- Characteristics of Step-Growth Polymerization
- Typical Step-Growth Reactions
- Ring Formation
- Nonlinear Step-Growth Reactions
- Statistical Derivation
- Comparison with Experiment
- Polyurethanes
- Thermosetting Polymers
- Free-Radical Addition Polymerization
- Addition Polymerization
- Choice of Initiators
- Free-Radical Polymerization
- Initiators
- Chain Growth
- Termination
- Steady-State Kinetics
- High-Conversion Bulk Polymerizations
- Chain Transfer
- Inhibitors and Retarders
- Activation Energies and the Effect of Temperature
- Thermodynamics of Radical Polymerization
- Heats of Polymerization
- Polymerization Processes
- Features of Free-Radical Polymerization
- Controlled Radical Polymerization
- Nitroxide-Mediated Polymerizations
- Atom Transfer Radical Polymerization (ATRP
- Reverse ATRP
- Degenerative Chain Transfer Reaction (DT)
- Reversible Addition Fragmentation Chain Transfer (RAFT)
- CRP of Vinyl Chloride
- The Kinetics of CRP Processes
- Application to Experimental Data
- Ionic Polymerization
- General Characteristics
- Cationic Polymerization
- Propagation by Cationic Chain Carriers
- Termination
- General Kinetic Scheme
- Energetics of Cationic Polymerization
- Telechelic Polymers via Cationic Polymerization
- Cationic Ring Opening Polymerization
- Stable Carbocations
- Anionic Polymerization
- Living Polymers
- Kinetics and Molar Mass Distribution in Living Anionic Systems
- Metal Alkyl Initiators
- Solvent and Gegen Ion Effects
- Anionic Ring-opening Polymerization
- Linear Copolymers and Other Architectures
- General Characteristics
- Composition Drift
- The Copolymer Equation
- Monomer Reactivity Ratios
- Reactivity Ratios and Copolymer Structure
- Monomer Reactivities and Chain Initiation
- Influence of Structural Effects on Monomer Reactivity Ratios
- The Q-e Scheme
- Alternating Copolymers
- Block Copolymer Synthesis
- Graft Copolymer Synthesis
- Statistical and Gradient Copolymers
- Complex Molecular Architectures
- Dendrimers
- Polymer Stereochemistry
- Architecture
- Orientation
- Configuration
- Geometric Isomerism
- Conformation of Stereoregular Polymers
- Factors Influencing Stereoregulation
- Homogeneous Stereospecific Cationic Polymerizations
- Homogeneous Stereoselective Anionic Polymerizations
- Homogeneous Diene Polymerization
- Summary
- Polymerization Reactions Initiated by Metal Catalysts and Transfer Reactions
- Polymerization Using Ziegler-Natta Catalysts
- Nature of Catalyst
- Nature of Active Centers
- Bimetallic Mechanism
- Monometallic Mechanism
- Stereoregulation
- Ring-Opening Metathesis Polymerization (ROMP)
- Monocyclic Monomers
- Bicyclo- and Tricyclomonomers
- Copolyalkenamers
- Living Systems
- Group Transfer Polymerization (GTP)
- Aldol Group Transfer Polymerization
- Metallocene Catalysts
- Concluding Remarks
- Polymers in Solution
- Thermodynamics of Polymer Solutions
- Ideal Mixtures of Small Molecules
- Nonideal Solutions
- Flory-Huggins Theory: Entropy of Mixing
- Enthalpy Change on Mixing
- Free Energy of Mixing
- Limitations of the Flory-Huggins Theory
- Phase Equilibria
- Flory-Krigbaum Theory
- Location of the Theta Temperature
- Lower Critical Solution Temperatures
- Solubility and the Cohesive Energy Density
- Polymer-Polymer Mixtures
- Kinetics of Phase Separation
- Polymer Characterization - Molar Masses
- Introduction
- Molar Masses, Molecular Weights, and SI Units
- Number-Average Molar Mass Mn
- End-Group Assay
- Colligative Properties of Solutions
- Osmotic Pressure
- Light Scattering
- Dynamic Light Scattering
- Viscosity
- Gel Permeation Chromatography
- Maldi
- Polymer Characterization - Chain Dimensions, Structures, and Morphology
- Average Chain Dimensions
- Freely Jointed Chain Model
- Short-range Effects
- Chain Stiffness
- Treatment of Dilute Solution Data
- Nuclear Magnetic Resonance (NMR)
- Infrared Spectroscopy
- Thermal Analysis
- Wide-Angle and Small-Angle Scattering
- Microscopy
- The Crystalline State and Partially Ordered Structures
- Introduction
- Mechanism of Crystallization
- Temperature and Growth Rate
- Melting
- Thermodynamic Parameters
- Crystalline Arrangement of Polymers
- Morphology and Kinetics
- Morphology
- Kinetics of Crystallization
- Block Copolymers
- Historical Development of Polymer Liquid Crystals
- Liquid Crystalline Phases
- Identification of the Mesophases
- Lyotropic Main-Chain Liquid Crystalline Polymers
- Thermotropic Main-Chain Liquid Crystal Polymers
- Side-Chain Liquid Crystalline Polymers
- Chiral Nematic Liquid Crystal Polymers
- The Glassy State and Glass Transition
- The Amorphous State
- The Glassy State
- Relaxation Processes in the Glassy State
- Glass Transition Region
- Theoretical Treatments
- Dependence of Tg on Molar Mass Structural Relaxation and Physical Aging
- Rheology and Mechanical Properties
- Introduction to Rheology
- The Five Regions of Viscoelastic Behavior
- The Viscous Region
- Mechanical Properties
- Mechanical Models Describing Viscoelasticity
- Linear Viscoelastic Behavior of Amorphous Polymers
- Dynamic Mechanical and Dielectric Thermal Analysis
- Time-Temperature Superposition Principle
- Dynamic Viscosity
- A Molecular Theory for Viscoelasticity
- The Reptation Model
- The Elastomeric State
- General Introduction
- Experimental Vulcanization
- Properties of Elastomers
- Thermodynamic Aspects of Rubberlike Elasticity
- Nonideal Elastomers
- Distribution Function for Polymer Conformation
- Statistical Approach
- Swelling of Elastomeric Networks
- Network Defects
- Resilience of Elastomers
- Structure-Property Relations
- General Considerations
- Control of Tm and Tg
- Relation between Tm andTg
- Random Copolymers
- Dependence of Tm andTg on Copolymer Composition
- Block Copolymers
- Plasticizers
- Crystallinity and Mechanical Response
- Application to Fibers, Elastomers, and Plastics
- Fibers
- Aromatic Polyamides
- Polyethylene
- Elastomers and Cross-Linked Networks
- Plastics
- High-temperature Speciality Polymers
- Carbon Fibers
- Concluding Remarks
- Polymers for the Electronics Industry
- Introduction
- Polymer Resists for IC Fabrication
- The Lithographic Process
- Polymer Resists
- Photolithography
- Electron Beam Sensitive Resists
- X-ray and Ion Sensitive Resists
- Electroactive Polymers
- Conduction Mechanisms
- Preparation of Conductive Polymers
- Polyacetylene
- Poly(P-phenylene)
- Polyheterocyclic Systems
- Polyaniline
- Poly(Phenylene Sulfide)
- Poly(1,6-heptadiyne)
- Applications
- Photonic Applications
- Light-Emitting Polymers
- Nonlinear Optics
- Langmuir-Blodgett Films
- Optical Information Storage
- Thermorecording on Liquid Crystalline Polymers
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